郭海心
作者： 来源： 2022-10-13
郭海心 研究员、博导
联系电话：022-6041277
个人主页：
https://orcid.org/0000-0002-0864-5845
https://scholar.google.com/citations?user=8HEmz3YAAAAJ&hl=zh-CN
研究领域
废弃物资源化利用、环境催化、绿色化学
个人简历
长期从事“秸秆等生物质高值资源化利用的新理论和新方法”的研究。2018年毕业于日本东北大学（Tohoku University）获得博士学位，历任日本东北大学助理教授（2018-2022）和日本临界流体研究中心研究员（2018-2022）。获得天津市优秀青年科技工作者；全球华人化工学者学会“未来化工学者”，中国农业科学院“农科英才”称号，天津市自然科学奖二等奖（木质纤维素高效解聚及高值化利用的绿色过程和机制，排名第四）、日本青年科学家科技奖（生物质资源高值化利用），日本化学工学会优秀发表奖。主持/参与国家自然科学基金、省部级项目等10余项，发表论文100余篇，授权发明专利10余项，主编中文专著1部（《秸秆高值资源化利用》，中国农业出版社，2023年），主编英文专著1部（Biofuels and Biorefineries-13，2024）。担任中国环境科学学会新污染物防治专委会委员、Biochar (IF=13.4) 等多个SCI期刊的青年编委或客座编辑。
科研项目
(1) 国家自然科学基金（No.2250080130），2026-2028，30万，主持
(2) 天津市自然科学基金（No.25JCYBJC00300），2026-2028，10万，主持
(3) 中国农科院级“农科英才”人才项目，2024.01-2028.12，400万，主持
(4) 中国农业科学院重大科技任务，2025.01-2027.12，参与
(5) 国家自然科学基金（No.22378215），2024-2027， 50万，参与
(6) 中央级公益性科研院所基础前沿项目(2022-jcqyrw-ghx)， 2022-2023, 20万， 主持
(7) 科技部项目，秸秆超临界流体处理技术引进与示范，2022.01-2023.12，24万，主持
(8) 日本学术振兴会 若手研究，“バイオマス酸化反応に向けた新規非貴金属触媒及び超臨界CO2-水二相系の開発” 2022-2024，455万日元， 主持
(9) 日本学术振兴会 若手研究，“二機能性触媒を超臨界CO2-イオン液体二相系で活用するバイオマスの選択的水素化” 2019-2021，429万日元， 主持
(10) 日本岩谷科学技術研究助成金，塩添加系イオン液体-超臨界CO2による機能性触媒を利用したバイオ化成品の開発，2021 -2022，200万日元，主持
(11) 日本文部科学省(项目号：JPMXP0219192801),ナノ材料の界面・構造制御プロセスサイエンス，2019-2025（阿屁 雅文教授主持），参与
(12) 日本学术振兴会基盘B(项目号：16H04549)，高効率バイオマス利用に向けた多機能性混合イオン液体-超臨界CO2システムの適用，2016-2019，（Richard Lee Smith, Jr教授主持）， 参与
学术论文
(1) Jianrong Shan, Bowen yang, Yaqiong Su, Gunhean Chong, Luqman Chuah Abdullah, Xinhua Qi*, Haixin Guo*, Microwave irradiation-assisted isomerization of glucose to fructose over Mg/Al-doped lignin self-assembled nanospheres, Applied Catalysis B: Environmental Energy, 379 (2025) 125682
(2) Xiaoping Wang, Bowen Yang, Haoye Wang, Haixin Guo*, Richard Lee Smith, Jr, Yaqiong Su, Xinhua Qi*, Enhanced hole-proton-coupled electron transfer of spin polarized photocatalyst via Mo-S4 coordination for sequential activation of C(sp3)-H and O-H bonds, Journal of Energy Chemistry, In Press
(3) Yiwei Tang, Bowen Yang, Haixin Guo*, Richard Lee Smith, Jr, Yaqiong Su, Xinhua Qi*, Structure-activity relationship for trimetallic CuCoZr catalyst in hydrogenolysis of furfural to 1,5-pentanediol, Chemical Engineering Journal, In Press
(4) Xiaoping Wang, Haixin Guo*, Xinhua Qi*, Recent advances in metal sulfide-based photocatalysts for biomass-based hydroxyl compounds valorization, Journal of Energy Chemistry, 109 (2025) 24-54
(5) Bowen Yang, Haiqing Zhang, Shihan Zhang, Haixin Guo*, Yaqiong Su, Xinhua Qi*, Enhanced peroxymonosulfate activation by CoFe doped carbon polyhedral nanocages through protecting-etching regulation for ciprofloxacin degradation, Chemical Engineering Journal, 521 (2025) 167159
(6) Bingkun Chen, Bowen Yang, Yaqiong Su, Qidong Hou, Richard Lee Smith, Jr, Xinhua Qi*, Haixin Guo*, NiFeCo wrinkled nanosheet electrode for selective oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid，Green Chemistry 27 (2025) 2117-2129
(7) Guanting Liao, Bowen Yang, Richard Lee Smith Jr., Haixin Guo*, Yaqiong Su, Xinhua Qi*, Coupled nitrate-to-ammonia reduction and persulfate production for ciprofloxacin removal via Cu2O/Cu nanorod and BDD electrodes, Journal of Hazardous Materials 496 (2025) 139331
(8) Hengyu Hao, Jiajiang Zhou, Li Tong*, Richard Lee Smith Jr., Feng Shen*, Haixin Guo*, PtZn alloy - N-doped biocarbon catalyst derived from rice straw for alkali-free glucose oxidation, Carbon 238 (2025) 120201
(9) Bingkun Chen, Qidong Hou, Richard Lee Smith Jr., Haixin Guo*, Xinhua Qi*, Electrocatalytic oxidation of biomass-derived furans to 2,5-furandicarboxylic acid – a review, Green Chemistry, 27 (2025) 8414-8447
(10) Ying Gao, Haojie Cui, Haixin Guo*, Effects of biochar pyrolysis temperature on soil carbon and nitrogen turnover and life cycle assessment, Plant and Soil (2025)
(11) Jiajiang Zhou, Bingkun Chen, Li Tong*, Gunhean Chong, Luqman Chuah Abdullah & Haixin Guo*, Recent advances of microwave-assisted deep eutectic solvent for lignocellulosic biorefining, Cellulose(2025)
(12) Xiaoping Wang, Bowen Yang, Haoye Wang, Haixin Guo*, Richard Lee Smith Jr, Yaqiong Su, Xinhua Qi*, Oxidation of 5-Hydroxymethylfurfural over ZnIn2S4/Ti3C2Tx Photocatalyst Modulated by Sulfur Vacancy Defects and Schottky Heterojunctions, ChemSusChem, (2025) e202501504
(13) Xue Li, Liangyu Li, Zulin Zhang, Yongfei Ma, Richard Lee Smith Jr., Haixin Guo*, Ran Zhao, Yiming Liu, Fengxia Yang*, Yongzhen Ding*, Insights into the mechanism of mechanically treated Fe/Mn-N doped seed meal hydrochar for efficient adsorption and degradation of tetracycline, Biochar, 7 (2025) 48
(14) Jiarui Wang*, Xiaocheng Wei, Yujun Shen*, Hao Kong, Weihan Wang, Richard Lee Smith Jr, Haixin Guo*, Mitigation of phosphorus contamination from livestock farms with La-containing hydrochar adsorbent, Separation and Purification Technology, 359 (2025) 130465.
(15) Yanyi Qi, Bingkun Chen, Haixin Guo#*, Critical advances in separation and purification of 5-hydroxymethylfurfural, Frontiers of Chemical Science and Engineering 19 (2025) 71.
(16) Yiwei, Tang, Richard Lee Smith, Jr, Bowen Yang, Haixin Guo*, Yaqiong Su, Xinhua Qi*, Efficient hydrogenolysis of furfuryl alcohol to 1,5-pentanediol over NiLa@ZrO2 catalyst, Chemical Engineering Journal, 508 (2025) 160967.
(17) Jianrong Shan#, Haixin Guo#*, Jiajiang Zhou, Feng Shen, Mo Qiu, Jirui Yang, Richard Lee Smith, Jr.*, Xinhua Qi*, Efficient isomerization of glucose to fructose over Al-loaded functional lignin biopolymer, Applied Catalysis B: Environmental Energy, 353 (2024) 124095.
(18) Bingkun Chen, Abe Yoya, Haixin Guo*, Richard Lee Smith, Jr*, Selective oxidation of 5-hydroxymethylfurfural over MnOx-CeO2 catalyst prepared with co-precipitation method, Fuel, 376 (2024) 132745
(19) Guangting Liao, Richard Lee Smith, Jr, Haixin Guo*, Xinhua Qi*, Review of carbon-based catalysts for electrochemical nitrate reduction and green ammonia synthesis, Green Chemistry, 26 (2024) 11797-11831.
(20) Haixin Guo, Xinhua Qi*, Deep eutectic solvents for synthesis of 5-hydroxymethylfurfural, Current Opinion in Green and Sustainable Chemistry, 47 (2024) 100924.
(21) Yingying Xu, Haixin Guo*, Xinhua Qi*, One-pot assembly of sulfated lignin/Zr coordination polymer for efficient alcoholysis of furfuryl alcohol to methyl levulinate, Renewable Energy, 229 (2024) 120742.
(22) Haixin Guo*, Yukiya Isoda, Tetsuo Honma, Feng Shen, Richard Lee Smith, Jr.*, Sustainably-derived sulfonated pinecone-based hydrochar catalyst for carbohydrate dehydration, Renewable Energy, 232 (2024) 121145.
(23) Siyu Xu#, Haixin Guo#, De Li, Hejuan Wu, Mo Qiu, Jirui Yang, Feng Shen*, Ball billing induced highly dispersed nano-MgO in biochar for glucose isomerization at low temperatures, Bioresource Technology, 406 (2024) 131071.
(24) Haiqing Zhang, Richard Lee Smith, Jr, Haixin Guo*, Xinhua Qi*, Cobalt cross-linked ordered mesoporous carbon as peroxymonosulfate activator for sulfamethoxazole degradation, Chemical Engineering Journal, 472 (2023) 145060.
(25) Yixuan Feng, Haixin Guo*, Richard Lee Smith, Jr, Xinhua Qi*, Electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid via metal-organic framework-structured hierarchical Co3O4 nanoplate arrays, Journal of Colloid and Interface Science 632 (2023) 87-94.
(26) Taishi Dowaki, Haixin Guo*, Richard Lee Smith, Jr.*, Cascade conversion and kinetic modeling of glucose transformation into mixed-biofuels via lignin-derived Lewis-Brønsted acid biochars, Renewable Energy, 217 (2023) 119204.
(27) Taishi Dowaki, Haixin Guo*, Richard Lee Smith, Jr.*, Lignin-derived biochar solid acid catalyst for fructose conversion into 5-ethoxymethylfurfural, Renewable Energy, 199 (2022) 1534-1542.
(28) Feng Shen, Ye Li, Xiaoye Qin, Haixin Guo*, Jialu Li, Jirui Yang, Yongzhen Ding*, Selective oxidation of cellulose into formic acid over heteropolyacid-based temperature responsive catalysts, Renewable Energy, 185 (2022) 139-146.
(29) Mengmeng Li, Menghan Feng, Changbin Guo, Shangkai Qiu, Lisheng Zhang, Di Zhao, Haixin Guo*, Keqiang Zhang, Feng Wang*, Green and efficient Al-doped LaFexAl1–xO3 perovskite oxide for enhanced phosphate adsorption with creation of oxygen vacancies, ACS Applied Materials & Interfaces, 15 (2023) 16942–16952.
(30) Yingying Xu, Yining Liang, Haixin Guo*, Xinhua Qi*, Catalytic hydrogenation of levulinic acid to γ-valerolactone over lignin-metal coordinated carbon nanospheres in water, International Journal of Biological Macromolecules, 240 (2023) 124451.
(31) Haixin Guo#, Jialu Li#, Siyu Xu, Jirui Yang, Gun-Hean Chong, Feng Shen*, Mo-modified MnOx for the efficient oxidation of high-concentration glucose to formic acid in water, Fuel Processing Technology 242 (2023) 107662.
(32) Yiwei Tang, Junyan Fu, Yicong Wang, Haixin Guo*, Xinhua Qi*, Bimetallic Ni-Zn@OMC catalyst for selective hydrogenation of levulinic acid to γ-valerolactone in water, Fuel Processing Technology 240 (2023) 107559.
(33) Hengyu Hao, Yuya Abe, Haixin Guo*, Xiao Zhang, Richard Lee Smith Jr*, Catalytic transfer hydrogenation and ethanolysis of furfural to ethyl levulinate using sulfonated Hf- or Ni-catalysts prepared with mixed solvents, ACS Sustainable Chemistry and Engineering, 10 (2022) 16261-16270.
(34) Haixin Guo*, Sohei Ogawa, Yukiya Isoda, Feng Shen, Richard Lee Smith, Jr.*, Weak-acid biochar catalyst prepared from mechanochemically-activated biomass and humic acid for production of 5-hydroxymethylfurfural, Biochar, 4 (2022) 42.
(35) Haixin Guo*, Taishi Dowaki, Feng Shen, Xinhua Qi, Richard Lee Smith, Jr.*, Critical assessment of reaction pathways for next-generation biofuels from renewable resources: 5-ethoxymethylfurfural, ACS Sustainable Chemistry & Engineering, 10 (2022) 9002-9021.
(36) Haixin Guo, Alif Duereh, Yaqiong Su, Emiel. J. M. Hensen, Xinhua Qi*, Richard Lee Smith, Jr.*, Mechanistic role of protonated polar additives in ethanol for selective transformation of biomass-related compounds, Applied Catalysis B: Environmental, 264 (2020) 118509.
参编/译著作
(1) 主编Production of Organic Acids and Alcohols from Agricultural Residues and Food Wastes （Biofuels and Biorefineries-13， Springier Nature）2024年
(2) 主编 秸秆高值转化利用技术 中国农业出版社 2023年
(3) 参编 秸秆预处理及组分分离技术 中国农业出版社 2025年
(4) 参编Algal Bioreactors: Vol 2, Elsevier (荷兰) 2024年
(5) 参编Production of Biofuels and Chemicals from Sustainable Recycling of Organic Solid Waste (Biofuels and Biorefineries-11，Springier Nature) 2022年
授权发明专利
(1) 郭海心，陈炳堃. 一种金属改性聚乙烯基功能炭材料及其制备方法和应用，专利号：ZL 2023 1 0793796.X
(2) 郭海心，姚正源，季晨曦，初仁生，刘柏松 .一种低灰分生物炭及其制备方法，专利号：ZL 2025 1 0495942.X
(3) 郭海心，陈炳堃. 一种镍-铁-钴三金属纳米阵列电催化剂、方法及其电催化氧 化5-羟甲基糠醛的应用，专利号：ZL202410804248.7
(4) 郭海心，郝珩羽，申锋. 一种磺酸基碳催化剂及其制备方法和应用，专利号：ZL20221 0201560.8
(5) 郭海心，郝珩羽，申锋. 一种糖酸合成用双金属复合生物炭催化剂及糖酸合成方法和应用，专利号：ZL 202310287388.7
(6) 郭海心，申锋. 一种磺酸基碳微球及其制备方法和应用，专利号：ZL202210543283.9
(7) 郭海心，王佳锐，魏孝承. 一种金属掺杂低共熔溶剂基水热炭及其制备方法和应用，专利号：ZL202311674454.2
(8) 郭海心，郝珩羽. 富含含氧官能团的多功能生物炭催化剂及制备方法，专利号：ZL202211075409.0
(9) 郭海心，单建荣. 一种复合材料木质素基水热碳及其制备方法和应用，专利号：ZL202411708026.1
荣誉与奖励
(1) 2022.02，天津市自然科学奖（二等奖） （排名第四）
(2) 2024.08，全球未来化工学者， 全球华人化工学会
(3) 2025.01，天津市优秀青年科技工作者，天津市青年科技工作者协会
(4) 2024.01，中国农业科学院“农科英才”，中国农业科学院
